(2.2.2-Cryptand)potassium tetra­carbonyl­cobaltate(−I)

نویسندگان

  • William W. Brennessel
  • John E. Ellis
چکیده

The title salt, [K(C18H36N2O6)][Co(CO)4], is an example of a classical carbonyl-metalate. The asymmetric unit contains one cation and one tetrahedral anion, both in general positions. Based on comparison of the four carbonyl C-O bond lengths and C-Co-C angles, the anion is unperturbed by the cation, which is normal for an alkali metal fully encased by a cryptand cage.

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عنوان ژورنال:

دوره 70  شماره 

صفحات  -

تاریخ انتشار 2014